By M Akaishi; Muki Zaishitsu Kenkyūjo.; et al
Read Online or Download Advanced materials '96 : new trends in high pressure research : proceedings of the 3rd NIRIM International Symposium on Advanced Materials (ISAM '96), Tsukuba, Japan, March 4-8, 1996 PDF
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Extra resources for Advanced materials '96 : new trends in high pressure research : proceedings of the 3rd NIRIM International Symposium on Advanced Materials (ISAM '96), Tsukuba, Japan, March 4-8, 1996
The mean diameter of colloidal Au was 3 nm and lower than the detection limit of X-ray equipment used. It is indicated that the gold particles was well dispersed on the ZnO support. According to the scherrer equation , the average size of ZnO support particles are about 26 nm calculated by MDI jade software. While, the size of calcined Au/ZnO catalysts was larger than the bare ZnO particles, increasing with the calcination temperature from 27 nm to 39 nm. In addition, the mean size of calcined 2% Au/ZnO catalyst calculated by XRD was well consistent with that by TEM.
3 Benzene conversion of Au/ZnO catalysts wth varying Au loadings at different temperatures. 10 g/m3, total flow rate: 20 ml/min. Effect of the Initial Benzene Concentration. In generally, the concentration of actual industrial exhausts and pollutants in the atmosphere varies at intervals, so it is necessary to consider the effect of inlet concentration on the benzene oxidation. The effects of the initial concentration of benzene on catalytic oxidation were investigated. 05 g/m3 during the whole temperature course.
This could be attributed to the following: multiple microelectrodes were caused by the ions including copper, zinc, stannum and nickel on the surface of the alloy. The electric potential difference of those microelectrode generated tiny batteries. 337 mv, respectively. It is easy for zinc to be oxidated as cathode losing electrons owing to its lowest standard electrode potential. The zinc ionization is as follows[7,8]: Zn → Zn2+ + 2e The reaction of positive pole consuming electrons is as follows: 2H+ + 2e → H2 The total reaction of the battery is as follows: Zn + 2H+ → Zn2+ + H2 With the conducting of the redox, the zinc on the surface of alloy was ionized continuously .
Advanced materials '96 : new trends in high pressure research : proceedings of the 3rd NIRIM International Symposium on Advanced Materials (ISAM '96), Tsukuba, Japan, March 4-8, 1996 by M Akaishi; Muki Zaishitsu Kenkyūjo.; et al